Biochar-Based Approaches for Heavy Metal Remediation in Agricultural Soils: Mechanisms, Optimization, and Emerging AI Applications

Abstract

Heavy metal contamination in agricultural soils poses persistent risks to crop safety and food-chain exposure. Although biochar is widely proposed—and increasingly applied—as a remediation amendment, field performance remains highly variable across soil constraints, metal speciation, and biochar designs. This review addresses this uncertainty by translating immobilization pathways (sorption/ complexation, precipitation, and redox-mediated stabilization) into a decision-oriented “mechanism–lever–endpoint” framework, thus linking mechanistic hypotheses to controllable engineering strategies such as feedstock selection, pyrolysis windows, and mineral/composite design. Beyond established plant–microbe interactions, there is a critical assessment of under-synthesized biochar–soil fauna pathways, with a focus on earthworms, and a reconciliation of conflicting evidence by highlighting boundary conditions that shift biological responses. Agronomic trade-offs and environmental risks are considered, associated with biochar production and application, emphasizing failure modes relevant to long-term soil health and remediation reliability. To support decision-grade deployment under heterogeneous evidence, a bias-aware AI-assisted workflow is outlined, which stresses standardized reporting, interpretability, and leakage-safe validation. Overall, the review integrates engineering options with biological synergies into a practical roadmap for more predictable and site-specific remediation in agricultural soils.