Hardwood-derived Cellulose Nanofibrils and Micro-Fibrillated Cellulose via Fenton Pretreatment: Issues of Fiber Fragmentation and Coating Performance

Abstract

A novel cellulose nano material was prepared through a controlled Fenton oxidation process utilizing hydrogen peroxide and ferrous ions. The reaction parameters enabled ferrous-catalyzed oxidation, which combined with mechanical treatment resulted in an effective fibrillation of cellulose fibers. Optical microscopy images provided a visual comparison of fiber morphology between untreated hardwood pulp and Fenton-treated samples, clearly illustrating the fibrillation effect. The samples were evaluated for fiber drainage behavior, and conclusions about accessibility and the extent of fibrillation were made. Measurements of the surface charge of the samples revealed an increase in negative charges originating from added carboxyl groups, which is essential for the dispersing and stabilization of cellulose nano fibrils and micro-fibrillated cellulose (CNF/MFC). Fourier-transform infrared spectroscopy (FTIR) confirmed the introduction of the carboxyl groups due to the Fenton treatment. The CNF/MFC material was used as paper coatings, without adding additional materials. The coated samples underwent analyses of permeability and roughness, revealing possibilities for enhancements in barrier properties and hydrophobicity. The results emphasize the ability of Fenton oxidation in generating high-quality small scale cellulosic materials with customized functionalities, underscoring their potential application in advanced coating technologies and sustainable material innovation.