Preparation and Papermaking Properties of Dry-Cut Powder from Chemically Crosslinked BEKP

Abstract

Chemical crosslinking of cellulosic fibers increases their brittleness, making them more susceptible to dry powdering. In this study, bleached eucalyptus kraft pulp (BEKP) sheets were crosslinked with glyoxal (GO) and citric acid (CA) and subsequently dry cut into powders using a Wiley cutting mill. Key variables in the powder preparation were dosages of GO and CA, as well as their respective catalysts, aluminum sulphate (alum) and sodium hypophosphite (SHP). The average fiber length of the GO and CA crosslinked pulps was reduced, at most down to 0.12 and 0.17 mm by the dry cutting, using a 0.5 mm perforated screen in the final dry-cutting stage. The powders exhibited reduced water retention, lower sedimentation volume in water, and, when dry, showed increased tapped and bulk densities. When mixed with refined BEKP, the powders enhanced dewatering during handsheet formation and improved the resulting sheets’ bulk, light scattering, and opacity, while reducing tensile strength. These findings suggest that chemically crosslinked pulp powders have potential as a bulking and dewatering aid in papermaking. Furthermore, due to their low water absorbency and presumable low abrasiveness, the powder may have potential applications beyond papermaking, such as filler of plastics, glues, and coating materials.