Influence of Maleic Anhydride Grafted Polypropylene on the Interfacial Compatibility of Wood Flour/Poly(β-Hydroxybutyrate Valerate) Composites
Keywords:
Wood-plastic composites (WPCs), Interfacial compatibility, Wood flour (WF), Poly(β-hydroxybutyrate valerate) (PHBV)Abstract
Maleic anhydride grafted polypropylene (MAPP) was utilized as a coupling agent to prepare composites of Populus tomentosa wood flour (WF) and poly (β-hydroxybutyrate valerate) (PHBV) through the hot-pressing process. The impacts of this coupling agent on the interfacial compatibility and physical-mechanical properties of WF/PHBV composites (WPHBVs) were analyzed and discussed by making use of scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetric analysis (TGA). The results indicated that after adding MAPP, a grafting reaction would occur. This reaction improved the interfacial compatibility between Populus tomentosa WF, and PHBV boosted the thermal stability of WPHBVs. When the addition amount of MAPP was 2%, the flexural strength and elastic modulus of WPHBVs reached their maximum levels, up to 27.99 MPa and 3690.47 MPa, respectively, and the strength enhancements were all above 40%. At this stage, the cross-section of the WPHBVs exhibited a smooth surface with no visible gaps. Tight interfacial bonding between phases indicated the highest level of compatibility between Populus tomentosa WF and PHBV.