Effect of Treating Birch Kraft Pulp with Peracetic Acid before O2-Delignification on the Properties of Pulp and Consumption of ClO2 in D0ED1 Bleaching

Abstract

The influence of pre-treating Kappa number of 18.0 industrial birch kraft pulp with peracetic acid (Paa) before oxygen delignification (OD) was studied relative to the pulps’ level of delignification, yield, brightness, intrinsic viscosity (IV), FS-number, tear index (TI), and the consumption of chlorine dioxide (ClO₂) in its subsequent Elemental Chlorine Free (ECF) bleaching. The study showed that such pretreatment is a way to extend the delignification of such pulp quite selectively in OD based on values of IV, FS-number, and TI, and to reduce significantly the consumption of ClO₂ required to bleach this pulp to a brightness of 87%. This reduction depended on the amount of Paa used for pulp pretreatment. For example, when 0.33% and 0.66% as active oxygen (A.O.) of Paa were used, ClO₂ consumption to bleach the pulp to 87% was lowered by 15.4% and 42.3%, respectively. As high as a 61.5% reduction in ClO₂ consumption in its bleaching could be obtained using 0.66% as A.O. on pulp and change of time of OD. This result allows for a significant decrease in the chlorine passing to the filtrates from washing the pulp after the D₀ and E stages to the pulp mill wastewater treatment plant.